Tris(spiroborate)-type anionic nanocycles.
Tris(spiroborate)-type anionic nanocycles.
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DOI：
10.1002/asia.201200162
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发表时间：
2012-07
期刊：
影响因子：
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通讯作者：
H. Danjo;Natsuyo Mitani;Y. Muraki;M. Kawahata;I. Azumaya;K. Yamaguchi;T. Miyazawa
中科院分区：
文献类型：
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作者：
H. Danjo;Natsuyo Mitani;Y. Muraki;M. Kawahata;I. Azumaya;K. Yamaguchi;T. Miyazawa
圆圈：合成了新型环状三（螺硼酸酯）作为纳米阳离子客体的分子识别模块。这些环番简单地通过用等摩尔量的硼酸处理相应的双（2，3-二羟基萘）来制备。以[Ir（tpy（2））]（3+）为阳离子客体，在溶液相和晶体相中测定了这些环状螺硼酸酯的分子识别能力.
Full circle: New cyclic tris(spiroborate)s were prepared as molecular recognition modules for nanometer-sized cationic guests. These cyclophanes were simply prepared by treating corresponding bis(2,3-dihydroxynaphthalene)s with an equimolar amount of boric acid. The molecular recognition ability of these cyclic spiroborates was estimated in solution and crystal phases by the use of [Ir(tpy(2))](3+) as a typical example of a cationic guest.