The Crystal Structure of (TMTTF)2ReO4

The Crystal Structure of (TMTTF)2ReO4
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(TMTTF)2ReO4 的晶体结构

DOI:
10.1246/bcsj.57.2025
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发表时间:
1984
影响因子:
4
通讯作者:
H. Inokuchi
H. Inokuchi
中科院分区:
化学3区
文献类型:
--
作者:
H. Kobayashi;A. Kobayashi;Y. Sasaki;G. Saito;H. Inokuchi

文献摘要

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(TMTTF)2ReO4晶体与其他(TMTTF) 2X化合物(X=ClO4, PF6, Br,···)呈同构。TMTTF分子面对面堆叠形成锯齿形柱。虽然(TMTTF)2ReO4的结构与类似化合物(TMTSF)2ReO4非常相似,但(TMTTF)2ReO4中松散的分子间接触表明(TMTTF)2ReO4中的分子间相互作用似乎比(TMTSF)2ReO4弱得多。
The crystal of (TMTTF)2ReO4 is isomorphous with the other (TMTTF) 2X compounds(X=ClO4, PF6, Br,···). TMTTF molecules are stacked face-to face to form a zig-zag column. Although the structure of (TMTTF)2ReO4 closely resembles that of the analogous compound, (TMTSF)2ReO4, the loose intermolecular contacts in (TMTTF)2ReO4 suggest that the intermolecular interaction appears to be much weaker than that in (TMTSF)2ReO4.