CONFORMATION OF ETHYLENE-GLYCOL STUDIED WITH PHOTOELECTRON-SPECTROSCOPY
CONFORMATION OF ETHYLENE-GLYCOL STUDIED WITH PHOTOELECTRON-SPECTROSCOPY
复制标题
DOI：
10.1088/0031-8949/21/2/010
复制
发表时间：
1980-01-01
期刊：
影响因子：
2.9
通讯作者：
SVENSSON, A
中科院分区：
文献类型：
--
作者：
KARLSSON, L;ASBRINK, L;SVENSSON, A
The photoelectron spectrum of the ethylene glycol (C 4 O 2 H 6) molecule is presented for the valence region up to 25 eV. Assignments of the electron bands are given with reference to the methanol and water molecules. A conformational analysis is performed by comparison between the experimentally determined ionization energies and those calculated for different conceivable geometries employing the HAM/3 method. It is found that the molecule possesses a gauche conformation with a twist angle of about 60 around the CC bond and that it has a single internal hydrogen bond.
