Insulated molecular wires: Synthesis of conjugated polyrotaxanes by Suzuki coupling in water

Insulated molecular wires: Synthesis of conjugated polyrotaxanes by Suzuki coupling in water
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DOI:
10.1002/1521-3773(20001002)39:19
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发表时间:
2000-01-01
影响因子:
16.6
通讯作者:
Anderson, HL
Anderson, HL
中科院分区:
化学1区
文献类型:
--
作者:
Taylor, PN;O'Connell, MJ;Anderson, HL

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Poly‐para‐phenylene polyrotaxane 1is the first conjugated polyrotaxane. The naphthalene end groups prevent theβ‐cyclodextrin rings from slipping off the conjugated backbone in solution. The matrix‐assisted laser desorption/ionization time‐of‐flight (MALDI‐TOF) mass spectrum shows a series of oligomers, up to a [10]rotaxane.