Fluorescent protein red Kaede chromophore; one-step, high-yield synthesis and potential application for solar cells

Fluorescent protein red Kaede chromophore; one-step, high-yield synthesis and potential application for solar cells
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荧光蛋白红色 Kaede 发色团;一步法高产合成及在太阳能电池中的潜在应用

DOI:
10.1039/b908542d
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发表时间:
2009-01-01
影响因子:
4.9
通讯作者:
Chou, Pi-Tai
Chou, Pi-Tai
中科院分区:
化学2区
文献类型:
--
作者:
Chuang, Wei-Ti;Chen, Bo-So;Chou, Pi-Tai

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在ZnCl_2催化下,绿色荧光蛋白(GFP)发色团与咪唑甲醛一步缩合,合成了红色的Kaede发色团及其衍生物(1a-d,2,3 > 70%),其中1a作为太阳能电池的染料具有一定的潜力,其转换效率(eta)为3.04%.
The one-step condensation between the Green Fluorescence Protein (GFP) chromophore and 1H-imidazole-5-carbaldehyde catalyzed by ZnCl2 proved to be a facile method to synthesize the red Kaede chromophore and its derivatives (1a-d, 2, and 3 > 70%), among which 1a then demonstrated its potential as a dye in solar cell, with a moderate conversion efficiency (eta) of 3.04%.