An ultrastable Zr metal–organic framework with a thiophene-type ligand containing methyl groups
An ultrastable Zr metal–organic framework with a thiophene-type ligand containing methyl groups
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DOI：
10.1039/c5ce00269a
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发表时间：
2015-05
期刊：
影响因子：
3.1
通讯作者：
Keke Wang;Hongliang Huang;Wenjuan Xue;Dahuan Liu;Xudong Zhao;Yuanlong Xiao;Zhengjie Li;Qingyuan Yang-Qing
中科院分区：
文献类型：
--
作者：
Keke Wang;Hongliang Huang;Wenjuan Xue;Dahuan Liu;Xudong Zhao;Yuanlong Xiao;Zhengjie Li;Qingyuan Yang-Qing
在pH=0-12的溶液和沸水中，由于甲基的空间位阻和电子效应以及强的Zr-O键，超稳定的金属-有机骨架可以保持完好。该MOF对Hg0水蒸气表现出良好的吸附和传感性能，这是由于噻吩类的存在。
An ultrastable metal–organic framework can remain intact in pH = 0 to 12 solutions and boiling water, attributed to the steric hindrance and electronic effect of methyl groups as well as strong Zr–O bonds. This MOF exhibits good adsorption and sensing performance for Hg0 vapor because of the presence of thiophene.