A regio- and stereodivergent synthesis of vic-amino alcohols
A regio- and stereodivergent synthesis of vic-amino alcohols
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DOI：
10.1021/ol006736i
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发表时间：
2000-11
期刊：
影响因子：
5.2
通讯作者：
B. Olofsson;U. Khamrai;P. Somfai
中科院分区：
文献类型：
--
作者：
B. Olofsson;U. Khamrai;P. Somfai
A regio- and stereodivergent synthesis of vic-amino alcohols starting from vinylepoxides is described. The developed strategy focuses on the propensity of vinylepoxides and vinylaziridines to be ring-opened at the allylic position by suitable nucleophiles and makes use of reactions that perform such tasks selectively with either retention or inversion of configuration.
