Copper nanoparticle-catalyzed borylation of alkyl bromides with an organodiboron compound
Copper nanoparticle-catalyzed borylation of alkyl bromides with an organodiboron compound
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DOI：
10.1039/c4ra05999a
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发表时间：
2014-01-01
期刊：
影响因子：
3.9
通讯作者：
Chung, Young Keun
中科院分区：
文献类型：
--
作者：
Kim, Ju Hyun;Chung, Young Keun
伯和仲烷基溴与双（频哪醇）二硼的硼基化在市售铜纳米颗粒作为催化剂的存在下进行。反应在室温下在不存在膦的情况下完成。该催化体系具有活性高、底物范围广、官能团耐受性好等特点。
Borylation of primary and secondary alkyl bromides with bis(pinaco-lato)diboron was carried out in the presence of commercially available copper nanoparticles as catalysts. The reaction went to completion in the absence of phosphines at room temperature. The catalytic system showed high activity, broad substrate scope, and good functional group tolerance.