Organometallic Chemistry - Volume 40
Organometallic Chemistry - Volume 40
复制标题
有机金属化学 - 第 40 卷
DOI：
10.1039/9781782623960-00001
复制
发表时间：
2015
期刊：
影响因子：
--
通讯作者：
Just-Baringo X
中科院分区：
文献类型：
--
作者：
Just-Baringo X
碘化钐（SmI2，Kagan试剂）是有机合成中最重要的还原剂之一。其独特的反应性和选择性使其成为介导靶向合成关键步骤的理想选择，通常提供其他试剂无法匹配的结果。在这篇综述中，我们提出了选定的例子，SmI2在靶向合成中的应用，在过去的四年中，并描述了使作用的试剂在天然产物，非天然生物活性化合物，和有机材料的建设中发挥。
Samarium (II) iodide (SmI2, Kagan’s reagent) is one of the most important reducing agents in organic synthesis. Its unique reactivity and selectivity makes it ideal for mediating key steps in target syntheses often providing outcomes that simply cannot be matched by other reagents. In this review we present selected examples of the application of SmI2 in target-oriented synthesis during the last four years and describe the enabling role the reagent has played in the construction of natural products, unnatural bioactive compounds, and organic materials.