A germanate built from a 6(8)12(6) cavity cotemplated by an (H2O)16 cluster and 2-methylpiperazine.
A germanate built from a 6(8)12(6) cavity cotemplated by an (H2O)16 cluster and 2-methylpiperazine.
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DOI：
10.1002/anie.200801375
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发表时间：
2008-09
影响因子：
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通讯作者：
Qinhe Pan;Jiyang Li;K. Christensen;Charlotte Bonneau;Xiaoyan Ren;Lei Shi;Junliang Sun;X. Zou
中科院分区：
文献类型：
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作者：
Qinhe Pan;Jiyang Li;K. Christensen;Charlotte Bonneau;Xiaoyan Ren;Lei Shi;Junliang Sun;X. Zou
全管状：在水（溶剂）热合成中，用2-甲基哌嗪和（H2O）16基团共模板制备了一种新的管状锗酸盐。锗酸盐具有一个巨大的、高度对称的68126空腔（见图；黄色球体），由12个Ge7X19 （X=O， OH， F）团簇（GeX6红色，GeX5黄色，GeX4绿色）组成。
Totally tubular: A new tubular germanate is cotemplated by 2-methylpiperazine and an (H2O)16 cluster in a hydro(solvo)thermal synthesis. The germanate features a large, highly symmetric 68126 cavity (see picture; yellow sphere) built from 12 Ge7X19 (X=O, OH, F) clusters (GeX6 red, GeX5 yellow, GeX4 green).