BREWER INTERMETALLIC PHASES AS SYNERGETIC ELECTROCATALYSTS FOR HYDROGEN EVOLUTION
BREWER INTERMETALLIC PHASES AS SYNERGETIC ELECTROCATALYSTS FOR HYDROGEN EVOLUTION
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DOI：
10.1016/0254-0584(89)90029-1
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发表时间：
1989-06-01
影响因子：
4.6
通讯作者：
JAKSIC, MM
中科院分区：
文献类型：
--
作者：
JAKSIC, MM
从理论上考虑了亚超d电子过渡金属的Brewer金属间相的成键有效性，并在相应的相图中实际研究了其作为析氢反应的电催化剂。Miedema的规则的金属间化合物相和它们的三元体系的反向稳定性也被用来解释，并与布鲁尔金属间化合物的协同电催化活性。该理论的基本概念显示和典型的相关问题实现的电催化活性作为金属间化合物的功能。氯酸盐电池过程中析氢的电催化问题及其基于布鲁尔金属间相的解决方案，也被认为是。
Brewer intermetallic phases of hypo-hyper-d-electronic transition metals have been theoretically considered in the light of their bonding effectiveness and practically investigated across the corresponding phase diagrams as e lectrocatalysts for the hydrogen evolution reaction. Miedema's rule of reversed stability of intermetallic phases and their ternary hydrides has also been employed to explain, and correlate with, the synergetic electrocatalytic activity of Brewer Intermetallics. Basic concepts of the theory are displayed and typical relevant issues of achieved electrocatalytic activity as a function of intermetallic composition are presented. The problem of electrocatalysis for hydrogen evolution in the chlorate cell process and its solution based on the Brewer intermetallic phases, are also considered.