TEMPERATURE-DEPENDENCE OF THE STRUCTURE FACTOR OF AS2SE3 GLASS UP TO THE GLASS-TRANSITION

TEMPERATURE-DEPENDENCE OF THE STRUCTURE FACTOR OF AS2SE3 GLASS UP TO THE GLASS-TRANSITION
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DOI:
10.1103/physrevlett.47.1848
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发表时间:
1981-01-01
影响因子:
8.6
通讯作者:
NAGEL, SR
NAGEL, SR
中科院分区:
物理与天体物理1区
文献类型:
--
作者:
BUSSE, LE;NAGEL, SR

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测定了玻璃态as2se3的结构因子对温度的依赖性。在第一个峰上发现了令人惊讶的结果,从40 K到玻璃化转变温度T g,强度大幅增加;相反,第二个峰在这个范围内减小。第一个峰对应于玻璃中的层间相关。它的增加表明了层的平滑,这可能导致层之间的滑动,从而降低了T g以上的粘度。
The temperature dependence of the structure factor of glassy As 2 Se 3 has been measured. Surprising results were found for the first peak, which shows a large increase in intensity from 40 K to the glass transition temperature, T g; in contrast the second peak decreases in this range. The first peak corresponds to interlayer correlation in the glass. Its increase indicates a smoothing of the layers which may lead to layers slipping past one another, thus decreasing the viscosity above T g.