Extension of ring closing metathesis methodology to the synthesis of carbocyclic methyl and silyl enol ethers

Extension of ring closing metathesis methodology to the synthesis of carbocyclic methyl and silyl enol ethers
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DOI:
10.1039/b208445g
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发表时间:
2002-01-01
影响因子:
4.9
通讯作者:
Daly, AM
Daly, AM
中科院分区:
化学2区
文献类型:
--
作者:
Aggarwal, VK;Daly, AM

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碳环甲基和甲硅烷基烯醇醚(TBDMS是最佳的)可以合成区域特定的闭环复分解使用的“第二代”格拉布钌卡宾催化剂与分子筛组合。
Carbocyclic methyl and silyl enol ethers (TBDMS is optimum) can be synthesised regiospecifically by ring closing metathesis using the 'second generation' Grubbs ruthenium carbene catalyst in combination with molecular sieves.