Fabrication and Degradation of Polyperoxides by a Radical Chain Process under Mild Conditions
Fabrication and Degradation of Polyperoxides by a Radical Chain Process under Mild Conditions
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温和条件下自由基链法制备和降解聚过氧化物
DOI：
10.1246/cl.2004.732
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发表时间：
2004
影响因子：
1.6
通讯作者：
Shuji Taketani
中科院分区：
文献类型：
--
作者：
A. Matsumoto;Shuji Taketani
我们以1，3-二烯化合物和氧为起始共聚单体，在温和的温度和压力条件下合成了新型的环境友好的可降解聚合物聚过氧化物。它们通过各种刺激以自由基链机制降解;例如，由物理（加热或辐照）、化学（氧化还原）和生物化学（酶促）刺激诱导的降解。
We have fabricated polyperoxides as new kinds of environment-friendly and degradable polymers using 1,3-diene compounds and oxygen as the starting comonomers under mild temperature and pressure conditions. They degrade ina radical chain mechanism by various stimuli; for example, degradation induced by physical (heating or irradiation), chemical (redox), and biochemical (enzymatic) stimuli.