MOVPE growth and characterization of high‐N content InGaPN alloy lattice‐matched to GaP

MOVPE growth and characterization of high‐N content InGaPN alloy lattice‐matched to GaP
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与 GaP 晶格匹配的高氮含量 InGaPN 合金的 MOVPE 生长和表征

DOI:
10.1002/pssc.200303505
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发表时间:
2003
期刊:
Physica Status Solidi (c)
影响因子:
--
通讯作者:
Y. Shiraki
Y. Shiraki
中科院分区:
--
文献类型:
--
作者:
S. Sanorpim;F. Nakajima;R. Katayama;Nobuhiro Nakadan;Tokuharu Kimura;K. Onabe;Y. Shiraki

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采用低压(60 Torr)金属有机气相外延(MOVPE)方法在GaP(001)衬底上生长了InxGa 1-xP 1-yNy(x = 17.6%,0 < y ≤ 8.7%)合金薄膜。研究了InGaPN薄膜的结构和光学性质。随着N的掺入,压缩应变的减少和强烈的红移的光致发光(PL)的峰值能量和PL激发(PLE)的吸收边被清楚地观察到。对于低N含量(0% ≤ y < 3.4%)的薄膜,残余应变充分弛豫。而当N浓度较高时(3.4% < y ≤ 8.7%),InGaPN层在差距(001)衬底上是相干生长的。获得了N含量高达7.4%的晶格匹配InGaPN薄膜,对应于610.8 nm(2.03 eV)的10 K吸收波长。(© 2003 WILEY-VCH Verlag GmbH & Co. KGaA,魏因海姆)
InxGa1−xP1−yNy (x = 17.6%, 0 < y ≤ 8.7%) alloy films have been grown on GaP(001) substrates by low-pressure (60 Torr) metalorganic vapor phase epitaxy (MOVPE). Structural and optical properties of the InGaPN films have been investigated. With incorporation of N, a reduction of compressive strain and a strong red shift in both the photoluminescence (PL) peak energy and the absorption edge of PL excitation (PLE) were clearly observed. The residual strain sufficiently relaxes for films with low N contents (0% ≤ y < 3.4%). Whereas, for higher N concentrations (3.4% < y ≤ 8.7%), the InGaPN layers were coherently grown on the GaP (001) substrates. Lattice-matched InGaPN films with N content as high as 7.4% corresponding to a 10 K absorption wavelength of 610.8 nm (2.03 eV) have been obtained. (© 2003 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)