Non-Classically Controlled Signs in a Circularly Polarised Luminescent Molecular Puppet: The Importance of the Wire Structure Connecting Binaphthyl and Two Pyrenes
Non-Classically Controlled Signs in a Circularly Polarised Luminescent Molecular Puppet: The Importance of the Wire Structure Connecting Binaphthyl and Two Pyrenes
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DOI：
10.1002/ejoc.201501316
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发表时间：
2016-01-01
影响因子：
2.8
通讯作者：
Imai, Yoshitane
中科院分区：
文献类型：
--
作者：
Nakabayashi, Kazuki;Kitamura, Sayaka;Imai, Yoshitane
两个光激发芘作为傀儡产生的圆偏振发光和蓝色圆偏振发光的圆二色性符号受C-2-对称联萘作为傀儡师的线结构控制。实验结果虽然与理论模拟存在差异，但为发光体的光激发和基态手性提供了合理的设计。
The circularly polarised luminescence and circular dichroism signs of the blue circularly polarised luminescence generated by two photoexcited pyrenes as puppets are controlled by the wire structure of the C-2-symmetric binaphthyl as puppeteer. The experimental results, though at variance with theoretical simulation, offer a rational design in the photoexcited and ground state chiralities of luminophores.