A Fluorescent Molecular Capsule with a Flexible Polyaromatic Shell for Detecting Monoterpene Compounds in Water

A Fluorescent Molecular Capsule with a Flexible Polyaromatic Shell for Detecting Monoterpene Compounds in Water
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具有柔性多芳香族外壳的荧光分子胶囊用于检测水中的单萜化合物

DOI:
10.1039/c5cc09647b
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发表时间:
2016
影响因子:
4.9
通讯作者:
M. Yoshizawa
M. Yoshizawa
中科院分区:
化学2区
文献类型:
--
作者:
A. Suzuki;K. Kondo;Y. Sei;M. Akita;M. Yoshizawa

文献摘要

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通过两亲性U形聚芳亚基在水中的定量自互补组装,形成了一种具有柔性荧光壳层的新型分子胶囊。该胶囊可完全包封多种非荧光单萜化合物(例如,薄荷酮、薄荷醇和对薄荷烷),并作为荧光超分子探针,用于在室温下通过水中的发射信号识别分析物的结构特性。
A new molecular capsule with a flexible fluorescent shell was formed by the quantitative self-complementary assembly of amphiphilic, U-shaped polyaromatic subunits in water. The capsule can fully encapsulate a variety of non-fluorescent monoterpene compounds (e.g., menthone, menthol, and p-menthane) in the hydrophobic cavity and act as a fluorescent supramolecular probe for recognizing the structural identity of the analytes by emissive signals in water at room temperature.