Nucleophilic trifluoromethylation using trifluoromethyl iodide.: A new and simple alternative for the trifluoromethylation of aldehydes and ketones

Nucleophilic trifluoromethylation using trifluoromethyl iodide.: A new and simple alternative for the trifluoromethylation of aldehydes and ketones
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DOI:
10.1021/ol016933x
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发表时间:
2001-12-27
期刊:
影响因子:
5.2
通讯作者:
Dolbier, WR
Dolbier, WR
中科院分区:
化学1区
文献类型:
--
作者:
Aït-Mohand, S;Takechi, N;Dolbier, WR

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[图解]提出了一种基于四(二甲氨基)乙烯(TDAE)光诱导还原三氟甲基碘的醛和酮的亲核三氟甲基化反应的新方法。
[GRAPHICS]A novel method for nucleophilic trifluoromethylation of aldehydes and ketones, based on photoinduced reduction of trifluoromethyl iodide by tetrakis(dimethylamino)ethylene (TDAE), is presented.