pH-responsive Dendritic Gelators

pH-responsive Dendritic Gelators
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DOI:
10.1246/cl.2012.92
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发表时间:
2012-01-05
期刊:
影响因子:
1.6
通讯作者:
Chen, Wen-Chang
Chen, Wen-Chang
中科院分区:
化学4区
文献类型:
--
作者:
Chen, Ching-Yi;Ito, Yumiko;Chen, Wen-Chang

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研究了用于DNA传感应用的阳离子带电树枝的pH响应性。在碱性条件下,第一代和第二代酰胺树枝状分子C1和G2形成水凝胶,但在酸性条件下水凝胶恢复到流体状态,这一过程是完全可逆的。此外,稀释后的Cl、G2和G3溶液的荧光对pH值也表现出很高的敏感性。
The pH responsibility of cationic charged dendrons, which were previously synthesized for DNA-sensing applications, was investigated. The first and second generation amide dendrons Cl and G2 formed hydrogels under basic conditions, but the hydrogel returned to the fluid state under acidic conditions; this process was completely reversible. In addition, the fluorescence of the diluted Cl, G2, and G3 solutions also showed a high sensitivity to the pH value.