In Situ, Simultaneous Irradiation and Monitoring of a Photocatalyzed Organic Oxidation Reaction in a TiO2-Coated NMR Tube.
In Situ, Simultaneous Irradiation and Monitoring of a Photocatalyzed Organic Oxidation Reaction in a TiO2-Coated NMR Tube.
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DOI：
10.1021/acs.joc.5b01001
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发表时间：
2015-10
期刊：
影响因子：
--
通讯作者：
A. Mills;C. O’Rourke
中科院分区：
文献类型：
--
作者：
A. Mills;C. O’Rourke
甲苯的半导体光催化（SPC）氧化在NMR光谱仪内进行，并使用光纤探针/漫射器提供UV光以激活NMR管内侧上的二氧化钛光催化剂涂层，同时原位监测反应。这样的系统具有很大的潜力，简单的快速筛选范围广泛的SPC介导的有机反应。
The semiconductor photocatalyzed (SPC) oxidation of toluene is performed inside an NMR spectrometer and the reaction is monitored simultaneously in situ, using a fiber optic probe/diffuser to provide the UV light to activate the titania photocatalyst coating on the inside of the NMR tube. Such a system has great potential for the simple rapid screening of a wide range of SPC mediated organic reactions.