Step-gradient capillary electrochromatography.
Step-gradient capillary electrochromatography.
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阶梯梯度毛细管电色谱。
DOI:
10.1039/a703175k
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发表时间:
1997
期刊:
影响因子:
--
通讯作者:
K. Bartle
中科院分区:
文献类型:
--
作者:
M. Euerby;D. Gilligan;C. Johnson;K. Bartle
The analytical benefits of using a step-gradient in capillary electrochromatography (CEC) are demonstrated. The application of step-gradient CEC to the analysis of six diuretics of widely differing lipophilicities was evaluated and shown to result in a marked reduction in the analysis time and an improvement in the peak shape for later-eluting lipophilic components. When the step-gradient approach was performed in an automated mode, the retention time RSD for repeated injections was below 1%.