Post-Functionalization: A Useful Method for the Synthesis of Donor-Func-tionalized N-Heterocyclic Carbene-Transition-Metal Catalysts
Post-Functionalization: A Useful Method for the Synthesis of Donor-Func-tionalized N-Heterocyclic Carbene-Transition-Metal Catalysts
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后官能化:一种合成供体官能化 N-杂环卡宾过渡金属催化剂的有用方法
DOI:
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发表时间:
2014
期刊:
影响因子:
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通讯作者:
邓亮
中科院分区:
文献类型:
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作者:
莫贞波;邓亮
Functionalized N-heterocyclic carbene ligands are particularly useful and widely applied ligands in transition-metal chemistry and catalysis. In this article we introduce an emerging synthetic method for functionalized N-heterocyclic carbene ligands developed from the reactivity study on cyclometalated N-hetero-cyclic carbene compounds, namely postfunctionalization. The status quo of this method for the preparation of novel donor-functionalized N-heterocyclic carbene complexes and their application in catalysis are discussed.