INFRARED STUDIES ON COMPLEXES OF MG++ WITH ADENOSINE PHOSPHATES

INFRARED STUDIES ON COMPLEXES OF MG++ WITH ADENOSINE PHOSPHATES
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DOI:
10.1021/ja01536a051
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发表时间:
1958-01-01
影响因子:
15
通讯作者:
WETTER, LR
WETTER, LR
中科院分区:
化学1区
文献类型:
--
作者:
EPP, A;RAMASARMA, T;WETTER, LR

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红外光谱获得的单,二和三磷酸腺苷和肌苷的存在和不存在的Mg++。二价阳离子的存在影响了腺苷的二磷酸和三磷酸的焦磷酸基团和嘌呤核。这些数据表明,这些二价离子与上述基团络合,但没有直接的证据,以获得复合物是否是分子内或分子间。
Infrared spectra were obtained for the mono-, di-and triphosphate of adenosine and inosine in the presence and in the absence of Mg++. The presence of the divalent cation affected the pyrophosphate group and the purine nucleus of the diand triphosphates of adenosine. The data suggest that these divalent ions complex with the above groups but no direct evidence is obtained as to whether the complex is intramolecular or intermolecular.