Coordination Self‐Assembly Processes Revealed by Collaboration of Experiment and Theory: Toward Kinetic Control of Molecular Self‐Assembly
Coordination Self‐Assembly Processes Revealed by Collaboration of Experiment and Theory: Toward Kinetic Control of Molecular Self‐Assembly
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DOI：
10.1002/tcr.202000124
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发表时间：
2020-11
期刊：
影响因子：
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通讯作者：
S. Hiraoka;Satoshi Takahashi;Hirofumi Sato
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文献类型：
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作者：
S. Hiraoka;Satoshi Takahashi;Hirofumi Sato
在科学和技术领域，实验和理论合作的重要性已经在许多例子中得到了证明。分子自组装过程是一个复杂的多步化学反应，发生在由大量中间体组成的反应网络中。本文介绍了我们开发的一种实验方法QASAP （quantitative analysis of self - assembly process）和一种数值方法NASAP (numerical analysis of self - assembly process)，该方法通过分析QASAP获得的实验数据来绘制详细的分子自组装途径，这也是我们开发的一种方法，并介绍了它们在Pd（II）介导的配位组装研究中的应用。此外，还证明了通过改变反应条件来预测分子自组装结果的可能性。最后，讨论了基于途径依赖自组装的人工分子自组装领域的未来发展方向，即分子自组装的动力学控制。
The importance of the collaboration of experiment and theory has been proven in many examples in science and technology. Here, such a new example is shown in the investigation of molecular self‐assembly process, which is a complicated multi‐step chemical reaction occurring in the reaction network composed of a huge number of intermediates. An experimental method, QASAP (quantitative analysis of self‐assembly process), developed by us and a numerical approach, NASAP (numerical analysis of self‐assembly process), that analyzes the experimental data obtained by QASAP to draw detail molecular self‐assembly pathways, which was also developed by us, are introduced, and their application to the investigation of Pd(II)‐mediated coordination assemblies are presented. Further, the possibility of the prediction of the outcomes of molecular self‐assembly by varying the reaction conditions is also demonstrated. Finally, a future direction in the field of artificial molecular self‐assembly based on pathway‐dependent self‐assembly, that is, kinetic control of molecular self‐assembly is discussed.