Synthesis and structure of a triptycene-based nanosized molecular cage.
Synthesis and structure of a triptycene-based nanosized molecular cage.
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DOI：
10.1021/jo7017526
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发表时间：
2007-10
期刊：
影响因子：
--
通讯作者：
Chun Zhang;Chuanning Chen
中科院分区：
文献类型：
--
作者：
Chun Zhang;Chuanning Chen
通过Eglington-Glaser偶联反应设计并高效合成了基于三蝶烯的纳米分子笼，并通过核磁共振、质谱和X射线分析确定了其结构。此外，还发现笼状分子在固态时可以堆积成微孔结构，并且1,3,5-三甲苯分子位于孔道中。
A triptycene-based nanosized molecular cage was designed and efficiently synthesized by Eglington-Glaser coupling reaction, and its structure was determined by NMR, MS spectrometry and X-ray analysis. Moreover, it was found that the cage molecules could pack into a microporous structure in the solid state and 1,3,5-trimethylbenzene molecules were located in the channels.