Taming furfuryl cations for the synthesis of privileged structures and novel scaffolds
Taming furfuryl cations for the synthesis of privileged structures and novel scaffolds
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DOI：
10.1039/c3ob40814k
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发表时间：
2013-01-01
影响因子：
3.2
通讯作者：
Ramasastry, S. S. V.
中科院分区：
文献类型：
--
作者：
Dhiman, Seema;Ramasastry, S. S. V.
呋喃基阳离子是通过高效的铋催化的糠醇反应生成的。这一系统的研究提供了关于呋喃基阳离子对亲核取代反应的反应性分布的洞察。新型的呋喃基阳离子的C-C、C-N、C-O和C-S成键反应已经被开发出来，从而为进一步的操作提供了一系列不同的构建块。
Furfuryl cations are generated via a highly efficient bismuth-catalyzed reaction of furfuryl alcohols. This systematic study provides insight on the reactivity profile of furfuryl cations towards nucleophilic substitution reactions. Novel C-C, C-N, C-O and C-S bond forming reactions of furfuryl cations have been developed, thus providing access to a diverse array of building blocks for further manipulations.