A new and highly selective turn-on fluorescent sensor with fast response time for the monitoring of cadmium ions in cosmetic, and health product samples
A new and highly selective turn-on fluorescent sensor with fast response time for the monitoring of cadmium ions in cosmetic, and health product samples
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DOI：
10.1016/j.saa.2016.03.011
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发表时间：
2016-06-15
影响因子：
4.4
通讯作者：
Zaryabi, Mohadeseh Hosseinpour
中科院分区：
文献类型：
--
作者：
Khani, Rouhollah;Ghiamati, Ebrahim;Zaryabi, Mohadeseh Hosseinpour
Cadmium (Cd) which is an extremely toxic could be found in many products like plastics, fossil fuel combustion, cosmetics, water resources, and wastewaters. It is capable of causing serious environmental and health problems such as lung, prostate, renal cancers and the other disorders. So, the development of a sensor to continually monitor cadmium is considerably demanding. Tetrakis(4-nitrophenyl)porphyrin, T(4-NO2-P)P, was synthesized and used as a new and highly selective fluorescent probe for monitoring cadmium ions in the "turn-on" mode. There was a linear relationship between fluorescence intensity and the concentration of Cd(II) in the range of 1.0 x 10(-6) to 1.0 x 10(-5) mol L-1 with a detection limit of 0276 mu M. To examine the most important parameters involved and their interactions in the sensor optimization procedure, a four-factor central composite design (CCD) combined with response surface modeling (RSM) was implemented. The practical applicability of the developed sensor was investigated using real cosmetic, and personal care samples. (C) 2016 Elsevier B.V. All rights reserved.
