Interface chemistry of conductive crystalline porous thin films
Interface chemistry of conductive crystalline porous thin films
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DOI：
10.1016/j.trechm.2023.03.002
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发表时间：
2023-04
影响因子：
15.7
通讯作者：
Mingshui Yao;Ken‐ichi Otake;Susumu Kitagawa
中科院分区：
文献类型：
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作者：
Mingshui Yao;Ken‐ichi Otake;Susumu Kitagawa
导电结晶型多孔材料近年来引起了人们极大的研究兴趣。CPM的薄膜不仅在其高度有序的骨架和晶界内提供了独特的载流子传输路径，而且还促进了客体物种的质量传输，这有助于在CPM和衬底材料之间创建协同界面。在此，我们对cCPM薄膜的设计策略进行了总结和归类，并重点介绍了基于cCPM薄膜的协同界面。具体而言，本综述分为以下三个部分：(I)共聚焦聚合物的种类和设计，(Ii)共聚焦聚合物薄膜的设计和表征以及协同界面的概念验证实例，以及(Iii)作为结论的展望。
Conductive crystalline porous materials (cCPMs) have recently experienced huge research interest. The thin films ofcCPMs not only offer unique charge carrier transport pathways within their highly ordered skeletons and grain boundaries but also facilitate mass transport of guest species, which aid in creating synergistic interfaces betweencCPM and substrate materials. Herein, we aim to summarize and categorize the design strategies oncCPM thin films and then highlight the synergistic interface based oncCPM thin films. Specifically, this review is organized into the following three parts: (i) the categories and design ofcCPMs, (ii) the design and characterization ofcCPM thin films and a proof-of-concept example of the synergistic interface, and (iii) the outlook as the conclusion.