Synthesis and structure of bismuth compounds bearing a sulfur-bridged bis(phenolato) ligand and their catalytic application to the solvent-free synthesis of propylene carbonate from CO2 and propylene oxide.
Synthesis and structure of bismuth compounds bearing a sulfur-bridged bis(phenolato) ligand and their catalytic application to the solvent-free synthesis of propylene carbonate from CO2 and propylene oxide.
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DOI：
10.1039/b819911f
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发表时间：
2009-02
影响因子：
4.9
通讯作者：
S. Yin;S. Shimada
中科院分区：
文献类型：
--
作者：
S. Yin;S. Shimada
合成了两种含硫桥接双（酚）配体的铋化合物，发现在室温下，在1atm CO(2)下，碘盐作为共催化剂存在下，对CO(2)和环氧丙烷无溶剂合成碳酸丙烯具有很高的催化活性和选择性。
Two bismuth compounds bearing a sulfur-bridged bis(phenolato) ligand were synthesized and found to show high catalytic activity and selectivity for solvent-free synthesis of propylene carbonate from CO(2) and propylene oxide in the presence of iodide salts as co-catalysts at room temperature under 1 atm CO(2).