meta-selective aromatic borylation as key step in the synthesis of poipuol
meta-selective aromatic borylation as key step in the synthesis of poipuol
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DOI：
10.1055/s-2008-1078449
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发表时间：
2008-07-16
影响因子：
2.6
通讯作者：
Koert, Ulrich
中科院分区：
文献类型：
--
作者：
Cordes, Jens;Wessel, Claas;Koert, Ulrich
报道了海洋天然产物多酚的合成方法。关键的反应序列由铱催化的间位选择性CH-硼基化，然后将所得的芳基硼酸酯转化为芳基氯组成。
A synthesis of the marine natural product poipuol is reported. The key reaction sequence consists of an iridium-catalyzed meta-selective CH-borylation followed by the conversion of the resulting arylboronic ester into an aryl chloride.