“Organic Metals”—The Intermolecular Migration of Aromaticity
“Organic Metals”—The Intermolecular Migration of Aromaticity
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“有机金属”——芳香性的分子间迁移
DOI：
10.1002/anie.197705191
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发表时间：
1977
影响因子：
--
通讯作者：
J. Perlstein
中科院分区：
文献类型：
--
作者：
J. Perlstein
对各种有机材料的导电性进行了综述，并对那些有效传输电荷的材料和那些不有效传输电荷的材料进行了比较。这一比较表明，最有效的导体包含的分子(a)其自由基离子在单电子氧化或还原时形成新的芳六体，(b)其芳香性可以通过混合价相互作用迁移。根据这些材料的化学性质和化学键相互作用在电子传递过程中的重要性，给出了电数据。讨论了几个新的例子，并探讨了进一步研究的方向。
The electrical conductivity of a wide variety of organic materials is reviewed and a comparison made between those materials which transport charge efficiently and those that do not. This comparison reveals that the most efficient conductors contain molecules (a) whose radical ions form a new aromatic sextet upon one-electron oxidation or reduction and (b) whose aromaticity can migrate by mixed-valence interaction. The electrical data are presented in light of the chemistry of these materials and the importance of chemical bonding interactions in the electron transport process. Several new examples are discussed and directions for further research explored.