Nitrogen-Substitution in the Flapping Wings of Cyclooctatetraene-Fused Molecules
Nitrogen-Substitution in the Flapping Wings of Cyclooctatetraene-Fused Molecules
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DOI：
10.1246/bcsj.20210164
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发表时间：
2021-06
影响因子：
4
通讯作者：
Kensuke Suga;T. Yamakado;Shohei Saito
中科院分区：
文献类型：
--
作者：
Kensuke Suga;T. Yamakado;Shohei Saito
新的含氮分子的合成方案已经被开发出来。建立了一种关键前体--二苯并[a，e]环辛四烯四胺的克级合成方法，用于设计扑动喹恶啉和扑动吩嗪酰亚胺。研究了氮取代对其光物理性质和粘度探测性能的影响，并与文献报道的挥发式蒽亚胺进行了比较。
New synthetic protocols to the nitrogen-embedded flapping molecules have been developed. Gram-scale synthesis of a key precursor, tetraamine of dibenzo[a,e]cyclooctatetraene has been established for designing flapping quinoxaline and flapping phenazineimide. The impact of the nitrogen substitution on the photophysical properties and the viscosity-probing function has been investigated in comparison with the reported flapping anthraceneimide.