Flexible Transparent Fluorinated Nanohybrid with Innovative Heat-resistance Property -New Technology Proposal for Fabrication of Transparent Materials using "Crystalline" Polymer-
Flexible Transparent Fluorinated Nanohybrid with Innovative Heat-resistance Property -New Technology Proposal for Fabrication of Transparent Materials using "Crystalline" Polymer-
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具有创新耐热性能的柔性透明氟化纳米杂化物-使用“结晶”聚合物制造透明材料的新技术提案-
DOI：
10.1002/polb.23889
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发表时间：
2015
期刊：
影响因子：
--
通讯作者：
A. Fujimori
中科院分区：
文献类型：
--
作者：
M. A. A. Mamun;Y. Soutome;Q. Meng;A. Fujimori
本研究提出了一种利用“结晶”聚合物生产透明材料的新技术。此外，还制造了具有高疏水表面和接近400 °C的热分解温度的耐热透明柔性塑料膜。具有配电板型层状结构的部分氟化结晶聚合物由于基于刚好低于250 °C熔点的高温拉伸形成高密度无定形结构而产生高透明度。与由具有高覆盖率的长链季鏻改性的蒙脱土熔融复合诱导形成保持透明性的纳米杂化物，并且还导致热降解温度增加超过50 °C。通过这种技术，它导致耐热性，透明度和灵活性，固态聚合物的纳米-微米-毫米结构是分层控制的，这使得新材料的创造成为可能。© 2015威利期刊公司. J.波利姆科学，部分B：聚合物物理2015年，53，1674-1690
A new technology for the production of transparent material, using a “crystalline” polymer, is proposed in this study. In addition, a heat‐resistant transparent flexible plastic film with a high hydrophobic surface and a thermal decomposition temperature near 400 °C was created. Partially fluorinated crystalline polymer with switchboard‐type lamellae results high transparency as a consequence of the formation of a high‐density amorphous structure based on high‐temperature drawing just below the melting point at 250 °C. Melt‐compounding with montmorillonite modified by the long‐chain quaternary phosphonium with high coverage induces formation of a nanohybrid that retains transparency and also results in an increase in the thermal degradation temperature by over 50 °C. Through this technology, which results in heat‐resistance, transparency, and flexibility, the nano‐micro‐millimeter structures of solid‐state polymers are hierarchically controlled, which enables the creation of new materials. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys.2015,53, 1674–1690