ELECTROCHEMICAL OXIDATION OF TRIFLUOROACETIC-ACID IN AN ORGANIC SUBSTRATE .3. PRESENCE OF SUBSTITUTED MALONIC-ACID HALF ESTERS AND UNSATURATED CARBOXYLIC-ACID ESTERS
ELECTROCHEMICAL OXIDATION OF TRIFLUOROACETIC-ACID IN AN ORGANIC SUBSTRATE .3. PRESENCE OF SUBSTITUTED MALONIC-ACID HALF ESTERS AND UNSATURATED CARBOXYLIC-ACID ESTERS
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DOI：
10.1139/v75-072
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发表时间：
1975-01-01
期刊：
影响因子：
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通讯作者：
CHAMPAGNE, PJ
中科院分区：
文献类型：
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作者：
RENAUD, RN;CHAMPAGNE, PJ
研究了三氟乙酸存在下取代丙二酸半酯的电化学氧化。得到了一些“交叉”Kolbe产物、一些不饱和烷氧羰基化合物、三氟甲基化双键加合物和三氟甲基化二聚体，并研究了烯属烷氧羰基化合物存在下三氟乙酸的电解。
The electrochemical oxidation of substituted malonic acid half-esters was studied in the presence of trifluoroacetic acid. Some 'crossed' Kolbe products were obtained together with some unsaturated carboalkoxy compounds, trifluoromethylated adducts to the double bond, and trifluoromethylated dimers.The electrolysis of trifluoroacetic acid in the presence of olefinic carboalkoxy compounds was also studied.