Application of Poly(butylenes 2-methylsuccinate) as Migration Resistant Plasticizer for Poly(vinyl chloride)

Application of Poly(butylenes 2-methylsuccinate) as Migration Resistant Plasticizer for Poly(vinyl chloride)
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聚2-甲基丁二酸丁二醇酯作为聚氯乙烯抗迁移增塑剂的应用

DOI:
10.1080/03602559.2013.845207
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发表时间:
2014-02
期刊:
Polymer - Plastics Technology and Engineering
影响因子:
--
通讯作者:
Wu, Yumin
Wu, Yumin
中科院分区:
其他
文献类型:
--
作者:
Xie, Tengteng;Gao, Chuanhui;Wang, Chuanxing;Shen, Shu'e;Wu, Yumin

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本研究成功地将生物基可生物降解聚酯聚2-甲基琥珀酸丁烯酯(PBM)作为高分子增塑剂对聚氯乙烯(PVC)进行了改性。研究了PVC/PBM共混物的拉伸性能、玻璃化转变温度的降低和断裂伸长率的提高对塑化效率的影响以及PBM的迁移稳定性。结果表明,与邻苯二甲酸二辛酯(DOP)增塑剂相比,PBM增塑剂的抗迁移性能显著提高。此外,其拉伸性能与PVC/DOP相当,表明环保型PBM可以作为替代增塑剂,以消除应用过程中迁移的邻苯二甲酸盐对健康的潜在风险。
The bio-based and biodegradable polyester poly(butylenes 2-methylsuccinate) (PBM) was successfully used as a polymeric plasticizer to modify poly(vinyl chloride) (PVC) in this work. The tensile properties, plasticization efficiency estimated by the lowered glass transition temperature and the enhanced elongation at break of the PVC/PBM blends and the migration stability of the PBM were investigated. It was indicated that the migration-resistant property of PVC plasticized with PBM was greatly superior to that with dioctyl phthalate (DOP). Furthermore, the tensile properties were comparable to that of PVC/DOP, indicating that the environmentally friendly PBM can be used as an alternative plasticizer to remove the potential health risks from migrating phthalates during applications.
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发表时间: 1983
影响因子: --
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