Oxygen chemisorption on Cu(110): A model for the c(6 x 2) structure.

Oxygen chemisorption on Cu(110): A model for the c(6 x 2) structure.
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Cu(110) 上的氧化学吸附:c(6 x 2) 结构的模型。

DOI:
10.1103/physrevlett.65.2027
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发表时间:
1990
影响因子:
8.6
通讯作者:
Robert L. Johnson
Robert L. Johnson
中科院分区:
物理与天体物理1区
文献类型:
--
作者:
R. Feidenhans'l;Francois Grey;M. Nielsen;F. Besenbacher;F. Jensen;E. Lægsgaard;I. Stensgaard;K. W. Jacobsen;J. Nørskov;Robert L. Johnson

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从扫描隧道显微镜、表面x射线- din反应实验和理论预测之间的相互作用中,导出了一个明确的Cu(110)-c(6x2)O表面重构的结构模型,其中10个Cu原子在c(6x2)单元格内,其中两个形成Cu上层结构。总的情况是,目前的重构以及Cu(110)-(2x1)O和Cu(100)(242& J2)R45 0重构是由Cu-0-Cu链沿[001]方向稳定的。c(6x2)结构的成核和生长优先发生在台阶上。
From an interplay between scanning tunneling microscopy, surface x-ray-diN'raction experiments, and theoretical predictions, an unequivocal structural model for the Cu(110)-c(6x2)O surface reconstruction is derived with ten Cu atoms within the c(6x2) unit cell, two of which form a Cu superstructure A general picture evolves in which the present as well as the Cu(110)-(2x 1)O and the Cu(100)(242& J2)R45 0 reconstructions are stabilized by Cu-0-Cu chains directed along the [001] direction. The nucleation and growth of the c(6x 2) structure occur preferentially at steps.