UV‐vis spectroscopy of gas‐phase ions
UV‐vis spectroscopy of gas‐phase ions
复制标题
气相离子的紫外可见光谱
DOI：
10.1002/mas.21726
复制
发表时间：
2023
影响因子：
6.6
通讯作者：
Tureček, František
中科院分区：
文献类型：
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作者：
Tureček, František
光解作用光谱学在扩展气相离子结构研究方面取得了很大进展。这篇综述涉及气相离子电子激发的各个方面，这些方面导致波长依赖的解离和通过荧光的光发射，主要覆盖光谱的紫外和可见区域。简要概述的原则和仪器的几个例子。综述的主要目的是收集和选择性地介绍紫外-可见光谱在稳定气相离子结构研究中的应用，以及光谱与离子迁移率，碰撞诱导解离和离子-离子反应的组合，从而产生活性中间体和电子能量转移。
Photodissociation action spectroscopy has made a great progress in expanding investigations of gas‐phase ion structures. This review deals with aspects of gas‐phase ion electronic excitations that result in wavelength‐dependent dissociation and light emission via fluorescence, chiefly covering the ultraviolet and visible regions of the spectrum. The principles are briefly outlined and a few examples of instrumentation are presented. The main thrust of the review is to collect and selectively present applications of UV‐vis action spectroscopy to studies of stable gas‐phase ion structures and combinations of spectroscopy with ion mobility, collision‐induced dissociation, and ion–ion reactions leading to the generation of reactive intermediates and electronic energy transfer.