Chemistry and kinetics of size-selected cobalt cluster cations at thermal energies. 2. Reactions with oxygen
Chemistry and kinetics of size-selected cobalt cluster cations at thermal energies. 2. Reactions with oxygen
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热能下选定尺寸的钴簇阳离子的化学和动力学。
DOI：
10.1021/j100196a015
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发表时间：
1992
期刊：
影响因子：
--
通讯作者：
A. Castleman
中科院分区：
文献类型：
--
作者：
B. Guo;K. P. Kerns;A. Castleman
利用在热能下运行的具有激光汽化源的选择离子漂移管（SIDT - LV）研究了Con⁺（n = 2 - 9）与O₂气相反应的尺寸依赖化学性质和动力学。观察到Con⁺对O₂表现出非常高的反应活性，并且这些团簇倾向于发生连续的氧化反应。
The size-dependent chemistry and kinetics of gas-phase reactions of Co n + (n=2-9) with O 2 are examined by using a SIDT-LV (selected ion drift tube with laser vaporization source) operated at thermal energies. Co n + are observed to display a very high reactivity toward O 2 , and the clusters tend to undergo successive oxidation reactions.