Effective and selective iodofunctionalisation of organic molecules in water using the iodine-hydrogen peroxide tandem

Effective and selective iodofunctionalisation of organic molecules in water using the iodine-hydrogen peroxide tandem
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DOI:
10.1039/b409919b
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发表时间:
2004-01-01
影响因子:
4.9
通讯作者:
Stavber, S
Stavber, S
中科院分区:
化学2区
文献类型:
--
作者:
Jereb, M;Zupan, M;Stavber, S

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使用水中的元素碘实现了有效的过氧化氢增强酮、1,3-二羰基衍生物和活化芳香族分子的碘官能化,而炔烃则立体选择性地转化为(E)-1,2-二碘烯烃。
Efficient hydrogen peroxide enhanced iodofunctionalisation of ketones, 1,3-dicarbonyl derivatives and activated aromatic molecules using elemental iodine in water is achieved, whereas alkynes were stereoselectively converted into (E)- 1,2-diiodoalkenes.