Is the translational diffusion of organic radicals different from that of closed-shell molecules?
Is the translational diffusion of organic radicals different from that of closed-shell molecules?
复制标题
有机自由基的平移扩散与闭壳分子的平移扩散不同吗？
DOI：
10.1002/chin.200052291
复制
发表时间：
2000
影响因子：
18.3
通讯作者：
M. Terazima
中科院分区：
文献类型：
--
作者：
M. Terazima
用瞬态光栅技术测量了光化学产生的中间自由基的平移扩散。这些中间体的扩散行为不同于已经被广泛研究的稳定分子的扩散行为。这些物种的扩散的调查将提供一个机会，以揭示独特的中间体和基质之间的分子间相互作用。这些信息对于理解溶液中的光化学是有价值的。
The translational diffusion of photochemically created intermediate radicals is measured by the transient grating technique. The diffusional behavior of these intermediates is different from that of stable molecules, which have already been investigated extensively. The investigation of the diffusion of these species will provide an opportunity to reveal the unique intermolecular interaction between the intermediates and matrix. This information will be valuable for understanding photochemistry in solutions.