Acid-catalysed intramolecular cobalt to nitrogen aryl migration and intramolecular reverse reaction in cobalt porphyrins. Synthesis of N-phenylporphyrins
Acid-catalysed intramolecular cobalt to nitrogen aryl migration and intramolecular reverse reaction in cobalt porphyrins. Synthesis of N-phenylporphyrins
复制标题
钴卟啉中酸催化分子内钴向氮芳基迁移和分子内逆反应。
DOI：
--
复制
发表时间：
1982
期刊：
影响因子：
--
通讯作者：
F. Metz
中科院分区：
文献类型：
--
作者：
H. Callot;F. Metz
苯钴(III)卟啉经酸处理生成N-苯基卟啉碱，而钴(II)金属化和还原则发生逆反应；双标记实验表明这两种迁移都是分子内的。
On acid treatment phenylcobalt(III)porphyrins yielded N-phenylporphyrin bases, while the reverse reaction was performed upon metallation by cobalt(II) and reduction; double labelling experiments showed that both migrations are intramolecular.