Solution-Processed Metallic Nanowire Electrodes as Indium Tin Oxide Replacement for Thin-Film Solar Cells

Solution-Processed Metallic Nanowire Electrodes as Indium Tin Oxide Replacement for Thin-Film Solar Cells
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DOI:
10.1002/adfm.201100457
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发表时间:
2011-12-20
影响因子:
19
通讯作者:
Brabec, Christoph J.
Brabec, Christoph J.
中科院分区:
材料科学1区
文献类型:
--
作者:
Krantz, Johannes;Richter, Moses;Brabec, Christoph J.

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溶液处理的银纳米线(Ag NW)薄膜被引入作为薄膜太阳能电池的透明电极。Ag NW电极在中等温度(低于100摄氏度)下通过在玻璃基板上的刮刀涂布来处理。这些电极的形态,光学和电学特性进行了研究作为一个功能的处理参数。对于太阳能电池应用,选择在450和800 nm之间具有90%的平均透明度和每平方10 Ω的薄层电阻率的Ag NW电极。发现Ag NW电极上的聚(3-己基噻吩-2,5-二基):[6,6]-苯基-C61-丁酸甲酯(P3 HT:PCBM)太阳能电池的性能与氧化铟锡上的其它相同电池的性能相匹配。总的来说,已经实现了在透明Ag NW电极上具有2.5%效率的P3 HT:PCBM太阳能电池。
Solution processed silver nanowire (Ag NW) films are introduced as transparent electrodes for thin-film solar cells. Ag NW electrodes were processed by doctor blade-coating on glass substrates at moderate temperatures (less than 100 degrees C). The morphological, optical, and electrical characteristics of these electrodes were investigated as a function of processing parameters. For solar-cell application, Ag NW electrodes with an average transparency of 90% between 450 and 800 nm and a sheet resistivity of 10 O per square were chosen. The performance of poly(3-hexylthiophen-2,5-diyl):[6,6]-phenyl-C61-butyric acid methyl ester (P3HT:PCBM) solar cells on Ag NW electrodes was found to match the performance of otherwise identical cells on indium tin oxide. Overall, P3HT:PCBM solar cells with an efficiency of 2.5% on transparent Ag NW electrodes have been realized.