Hydrogen-bonded nickel(I) complexes.
Hydrogen-bonded nickel(I) complexes.
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DOI:
10.1039/d0cc07216h
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发表时间:
2021-01-26
期刊:
影响因子:
--
通讯作者:
Szymczak NK
中科院分区:
文献类型:
--
作者:
Wilson JR;Zeller M;Szymczak NK
A series of nickel(II) tris(2-pyridylmethyl)amine (TPA) complexes featuring appended hydrogen bonds (H-bonds) to halides (F, Cl, Br) was synthesized and charcterized. Reduction to the corresponding nickel(I) state provided access to an unusual nickel(I) fluoride complex stabilized by H-bonds, enabling structural and spectroscopic characterization. Secondary-sphere hydrogen bonds enable structural characterization and evaluation of an unusual nickel(I) fluoride complex.
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