Chemoselective epoxidation of ene-ynamides:: Intramolecular cyclopropanation induced by the intermediate α-oxocarbene

Chemoselective epoxidation of ene-ynamides:: Intramolecular cyclopropanation induced by the intermediate α-oxocarbene
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DOI:
10.1055/s-2007-990841
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发表时间:
2007-11-09
期刊:
影响因子:
2
通讯作者:
Cossy, Janine
Cossy, Janine
中科院分区:
化学4区
文献类型:
--
作者:
Couty, Sylvain;Meyer, Christophe;Cossy, Janine

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三键酰胺的化学选择性环氧化反应产生α -氧羰基中间体,影响烯烃的分子内环丙烷化。
Chemoselective epoxidation of the triple bond of eneynamides generates an alpha-oxocarbene intermediate that effects the intramolecular cyclopropanation of the alkene.