THE BASIS OF THE ELECTRON THEORY OF METALS, WITH SPECIAL REFERENCE TO THE TRANSITION METALS
THE BASIS OF THE ELECTRON THEORY OF METALS, WITH SPECIAL REFERENCE TO THE TRANSITION METALS
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DOI：
10.1088/0370-1298/62/7/303
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发表时间：
1949-01-01
期刊：
影响因子：
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通讯作者：
MOTT, NF
中科院分区：
文献类型：
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作者：
MOTT, NF
它表明，集体电子和伦敦-海特勒模型是不被视为不同的近似相同的确切波函数的固体中，根据前一个模型，有一个部分填充区的能级。因此，可以说明为什么纯态的氧化镍是非导体，尽管它包含一个不完整的区域。根据这些结果讨论了金属镍、钯和铂的性质;铂与镍的不同之处在于，对基本磁体的磁矩的轨道贡献是不淬灭的。讨论给出的X射线吸收边，它示出了为什么激子线是缺席的金属。
It is shown that the collective electron and London-Heitler models are not to be regarded as different approximations to the same exact wave function for solids in which, according to the former model, there is a partially filled zone of energy levels. It can thus be shown why nickel oxide in the pure state is a non-conductor, although it contains an incomplete zone. The properties of the metals nickel, palladium and platinum are discussed in the light of these results; platinum differs from nickel in that the orbital contribution to the moment of the elementary magnets is not quenched. A discussion is given of x-ray absorption edges, and it is shown why exciton lines are absent for metals.