Lewis acid promoted carbon-carbon bond cleavage of γ-silyloxy-β-hydroxy-α-diazoesters
Lewis acid promoted carbon-carbon bond cleavage of γ-silyloxy-β-hydroxy-α-diazoesters
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DOI：
10.1021/ja801004d
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发表时间：
2008-03-26
影响因子：
15
通讯作者：
Brewer, Matthias
中科院分区：
文献类型：
--
作者：
Draghici, Cristian;Brewer, Matthias
环状γ-甲硅烷氧基-β-羟基-α-重氮酯在用四氯化鳍处理时经历C β-C γ键的有效断裂，以提供高凝胶的栓系醛炔酸酯产物。
Cyclic gamma-silyloxy-beta-hydroxy-alpha-diazoesters undergo efficient rupture of the C beta-C gamma bond when treated with fin tetrachloride to provide tethered aldehyde ynoate products in high geld.