Low-Coordinate Homoleptic Iron(II) Thiolates Revisited

Low-Coordinate Homoleptic Iron(II) Thiolates Revisited
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低配位均配铁(II)硫醇盐的再研究

DOI:
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发表时间:
1997
期刊:
影响因子:
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通讯作者:
J. Silver
J. Silver
中科院分区:
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文献类型:
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作者:
David J Evans;D. Hughes;J. Silver

文献摘要

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重新解释穆斯堡尔和晶体学数据,连同一些新的穆斯堡尔结果,提出了低坐标铁(II)硫代酸盐。结果表明,在某些情况下,铁的配位几何是最好的。此外,穆斯堡尔异构体移位和四极分裂可以区分低配位铁配合物中铁的配位几何,但不是先前提出的方式。
A reinterpretation of the Mossbauer and crystallographic data, together with some new Mossbauer results, is presented for low-coordinate iron(II) thiolates. It is shown that the coordination geometry about iron is best reassigned in some cases. Further, Mossbauer isomer shift and quadrupole splitting can distinguish the coordination geometry about iron in low-coordinate iron complexes, but not in the way previously proposed.