Stereoselective cyclization using palladium(II) catalyst via hemiacetal intermediates
Stereoselective cyclization using palladium(II) catalyst via hemiacetal intermediates
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DOI：
10.1016/j.tetlet.2004.02.058
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发表时间：
2004-03-29
影响因子：
1.8
通讯作者：
Hirai, Y
中科院分区：
文献类型：
--
作者：
Miyazawa, M;Hirose, Y;Hirai, Y
开发了 3-苯基-7-羟基-5-庚烯醛的立体选择性钯催化环化。进行反应得到具有高度受控的4,6-顺式立体化学的2,4,6-三取代四氢吡喃。 (C) 2004 Elsevier Ltd. 保留所有权利。
A stereoselective palladium-catalyzed cyclization of 3-phenyl-7-hydroxy-5-heptenal was developed. The reaction was carried out to give 2,4,6-trisubstituted tetrahydropyran with highly controlled 4,6-cis stereochemistry. (C) 2004 Elsevier Ltd. All rights reserved.