Tetra-n-butylammonium Iodide Catalyzed C-H Azidation of Aldehydes with Thermally Stable Azidobenziodoxolone
Tetra-n-butylammonium Iodide Catalyzed C-H Azidation of Aldehydes with Thermally Stable Azidobenziodoxolone
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DOI：
10.1021/acs.orglett.5b02543
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发表时间：
2015-11-06
期刊：
影响因子：
5.2
通讯作者：
Saito, Akio
中科院分区：
文献类型：
--
作者：
Shinomoto, Yukino;Yoshimura, Akira;Saito, Akio
四正丁基碘化铵在室温下可以有效催化醛 C-H 键与热稳定的叠氮苯并氧杂环酮的直接叠氮化。与需要过量高爆炸性叠氮化物源的传统方法相比，这是一种安全且方便的程序。
Tetra-n-butylammonium iodide can efficiently catalyze direct azidation of aldehyde C-H bonds with thermally stable azidobenziodoxolone at room temperature. Compared to conventional methods, which require excessive amounts of highly explosive azide sources, this is a safe and convenient procedure.