Effect of thermal annealing on luminescence properties of Eu,Mg-codoped GaN grown by organometallic vapor phase epitaxy

Effect of thermal annealing on luminescence properties of Eu,Mg-codoped GaN grown by organometallic vapor phase epitaxy
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DOI:
10.1063/1.4800447
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发表时间:
2013-04-08
影响因子:
4
通讯作者:
Fujiwara, Yasufumi
Fujiwara, Yasufumi
中科院分区:
物理与天体物理2区
文献类型:
--
作者:
Lee, Dong-gun;Wakamatsu, Ryuta;Fujiwara, Yasufumi

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研究了热退火对有机金属气相外延生长的Eu,Mg共掺杂GaN(GaN:Eu,Mg)的影响。在氮气氛中退火后,Eu-Mg相关的光致发光发射猝灭到13%,而光谱形状没有变化。在随后的氨气氛中退火后,淬灭的发射恢复到原始强度的65%。结合激发发射光谱和时间分辨光致发光的结果表明,猝灭行为归因于非钝化Mg受体诱导的Eu离子的激发4f电子的弛豫的非辐射过程。(C)2013年美国物理学会。
The effects of thermal annealing on Eu,Mg-codoped GaN (GaN:Eu,Mg) grown by organometallic vapor phase epitaxy were investigated. After annealing in nitrogen ambient, Eu-Mg related photoluminescence emission was quenched to 13% without a change in the spectral shape. The quenched emission recovered to 65% of the original intensity after a subsequent annealing in ammonia ambient. Combined excitation emission spectroscopy and time-resolved photoluminescence results revealed that the quenching behavior is attributed to a nonradiative process induced by unpassivated Mg acceptors in the relaxation of excited 4f electrons of Eu ions. (C) 2013 American Institute of Physics.